DIASTEREOSELECTIVE SYNTHESIS OF HETEROSUBSTITUTED ORGANOGEMBISMETALLIC REAGENTS - APPLICATION TO A NEW PROPARGYLMETALATION REACTION OF VINYL METALS

Brasseur D.; Normant JF.; Marek I.

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DIASTEREOSELECTIVE SYNTHESIS OF HETEROSUBSTITUTED ORGANOGEMBISMETALLIC REAGENTS - APPLICATION TO A NEW PROPARGYLMETALATION REACTION OF VINYL METALS

机译：非取代取代的有机宝石-金属间苯二酸酯的非对映选择性合成-在乙烯基金属新的炔丙基化反应中的应用

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The allylzincation and propargylzincation of various gamma-heterosubstituted vinyl metals proceed diastereoselectively. This represents a new synthetic approach to construct two or three adjacent stereogenic centers in acyclic systems. Copyright (C) 1996 Elsevier Science Ltd [References: 28]

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《Tetrahedron 》 |1996年第21期| 共16页
作者
Brasseur D.; Normant JF.; Marek I.;
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正文语种 eng
中图分类有机化学 ;
关键词
Dimetallic organic-compounds; Zinc; Alcohols;

机译：双金属有机化合物;锌;酒精;

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1. DIASTEREOSELECTIVE SYNTHESIS OF HETEROSUBSTITUTED ORGANOGEMBISMETALLIC REAGENTS - APPLICATION TO A NEW PROPARGYLMETALATION REACTION OF VINYL METALS [J] . Brasseur D., Normant JF., Marek I. Tetrahedron . 1996 ,第21期

机译：非取代取代的有机宝石-金属间苯二酸酯的非对映选择性合成-在乙烯基金属新的炔丙基化反应中的应用
2. Synthesis and Reactions of Allylic,Allenic,Vinylic,and Arylmetal Reagents from Halides and Esters via Transient Organopalladium Intermediates [J] . James A.Marshall Chemical Reviews . 2000 ,第8期

机译：卤化物和酯的瞬态有机钯中间体合成烯丙基，烯丙基，Vinylic和芳基金属试剂
3. Diastereoselective 1,2-Addition of Organometallic Reagents to Chiral Formylferrocenes Leading to Enantiomerically Pure Ferrocenyl Amino Alcohols: Application to Asymmetric Dialkylzinc Addition to Aldehydes and Synthesis of Optically Active 1,2-Homodi [J] . Shin-ichi Fukuzawa, Daisuke Tsuchiya, Kae Sasamoto, European journal of organic chemistry . 2000 ,第16期

机译：有机金属试剂的非对映选择性1,2-加成反应生成对映体纯的二茂铁基氨基醇的手性甲酰基二茂铁：在醛的不对称二烷基锌加成反应中的应用和光学活性的1,2-Homodi
4. SIMULTANEOUS SYNTHESIS OF π-CONJUGATED POLYMERS POSSESSING MULTIPLE ELEMENTS-BLOCKS BY REACTIONS OF ORGANOMETALLIC POLYMERS HAVING TITANACYCLOPENTADIENE MOIETIES WITH PLURAL REAGENTS [C] . Y. Matsumura, H. Nishiyama, S. inagi, IUPAC 10th International conference on novel materials and their synthesis: Book of abstracts . 2014

机译：具有多环戊二烯三环戊二烯基部分的有机金属聚合物的反应同时合成具有多个元素嵌段的π共轭聚合物
5. Part A. Diastereoselective synthesis of protected secondary amines via reduction /alkylation or deprotonation /alkylation of N-diphenylphosphinylimines. Part B. Synthesis of secondary amines via 1,2-addition of organometallic reagents to N-diphenylphosphinylimines and subsequent alkylation [D] . Shin, Hyunshun 2001

机译：A部分：通过N-二苯基膦亚胺的还原/烷基化或去质子化/烷基化的非对映选择性合成保护的仲胺。 B部分：通过将有机金属试剂1,2-加成到N-二苯基膦亚胺和随后的烷基化反应来合成仲胺
6. Three-Component Coupling Reactions of Silyl Glyoxylates Vinyl Grignard Reagent and Nitroalkenes: An Efficient Highly Diastereoselective Approach to Nitrocyclopentanols [O] . Gregory R. Boyce, Jeffrey S. Johnson -1

机译：甲硅烷基甲氧化甲硅烷基乙烯基格氏试剂和Nitroallenes的三组分偶联反应：对硝化萘酚的有效高度不映射的方法
7. Highly Diastereoselective Reaction of Chiral o-(2-(1,3-Oxazolidinyl))benzaldehydes with Alkylmetallic Reagents: Synthesis of Chiral 3-Substituted Phthalides. [O] . Hiroshi TAKAHASHI, Takeshi TSUBUKI, Kimio HIGASHIYAMA 1991

机译：具有烷基化合物试剂的手性O-（2-（1,3-恶唑烷基））苯甲醛的高度映选择性反应：手性3取代的邻苯二甲酸酯的合成。

DIASTEREOSELECTIVE SYNTHESIS OF HETEROSUBSTITUTED ORGANOGEMBISMETALLIC REAGENTS - APPLICATION TO A NEW PROPARGYLMETALATION REACTION OF VINYL METALS

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