DIASTEREOSELECTIVE SYNTHESIS OF VINYLMORPHOLINES BY PALLADIUM-CATALYZED TANDEM ALLYLIC SUBSTITUTIONS USING ENANTIOPURE AMINOALCOHOLS AS BIFUNCTIONAL NUCLEOPHILES

Thorey C.; Henin F.; Martens J.; Mehler T.; Muzart J.; Wilken J.

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DIASTEREOSELECTIVE SYNTHESIS OF VINYLMORPHOLINES BY PALLADIUM-CATALYZED TANDEM ALLYLIC SUBSTITUTIONS USING ENANTIOPURE AMINOALCOHOLS AS BIFUNCTIONAL NUCLEOPHILES

机译：钯催化的串联烯丙基取代基对映体氨基醇为双官能团的非对映体合成乙烯基钼的反应

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Enantiopure vinylmorpholines have been prepared by a diastereoselective disubstitution (de up to 92%) of (Z) ROCH(2)CH=CHCH(2)OR (R = Ac, CO(2)Me) by aminoalcohols in the presence of palladium catalysts. [References: 23]

机译：对映体纯的乙烯基吗啉是在钯催化剂存在下通过氨基醇通过非对映选择性分解（高达92％）的（Z）ROCH（2）CH = CHCH（2）OR（R = Ac，CO（2）Me）制备的。 [参考：23]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1995年第31期|共4页
作者
Thorey C.; Henin F.; Martens J.; Mehler T.; Muzart J.; Wilken J.;
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正文语种 eng
中图分类有机化学;
关键词
Ketonization; Construction; Morpholines; Enol;

机译：酮化;建筑;吗啉;烯醇;

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1. DIASTEREOSELECTIVE SYNTHESIS OF VINYLMORPHOLINES BY PALLADIUM-CATALYZED TANDEM ALLYLIC SUBSTITUTIONS USING ENANTIOPURE AMINOALCOHOLS AS BIFUNCTIONAL NUCLEOPHILES [J] . Thorey C., Henin F., Martens J., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第31期

机译：钯催化的串联烯丙基取代基对映体氨基醇为双官能团的非对映体合成乙烯基钼的反应
2. Highly regio- and diastereoselective palladium-catalyzed allylic substitution. Synthesis of 3-(2-aminobutylidene)4-arylazetidin-2-ones [J] . Cardillo G, Fabbroni S, Gentilucci L, Advanced synthesis & catalysis . 2005,第6期

机译：高度区域选择性和非对映选择性的钯催化的烯丙基取代。 3-（2-氨基丁烯）4-芳基氮杂环丁烷-2-酮的合成
3. Stereodivergent synthesis of 1,4-bifunctional compounds by regio- and diastereoselective Pd-catalyzed allylic substitution reaction [J] . Maezaki N, Yano M, Hirose Y, Tetrahedron . 2006,第44期

机译：区域和非对映选择性钯催化的烯丙基取代反应的立体发散合成1,4-双功能化合物
4. Hydroxyapatite-supported Palladium-catalyzed Allylation of Carbon Nucleophiles with Allylic Carbonates [C] . Yukiko Nakajima, Yoshiro Masuyama Symposium on Organometallic Chemistry . 2007

机译：羟基磷灰石支持的钯催化碳亲核催化烯丙基碳酸酯
5. A. Studies In The Allylic Substitution Chemistry Of Copper Hydride B. Stereoselective Silylcupration Of Conjugated Alkynes In Micellar Media C. Palladium-Catalyzed Synthesis Of 1,3-Butadienes and [3]-[6]Dendralenes D. Synthesis Of Small Molecule Underwater Adhesives Inspired By Mussels. [D] . Linstadt, Roscoe T. H. 2017

机译：A.氢化铜的烯丙基取代化学的研究B.共轭炔烃在胶束介质中的立体选择性甲硅烷基化C.钯催化的1,3-丁二烯和[3]-[6] Dendralenes的合成D.小分子水下胶粘剂的合成受贻贝启发。
6. Palladium-Catalyzed Chemoselective Allylic Substitution Suzuki-Miyaura Cross-Coupling and Allene Formation of Bifunctional 2-B(pin)-Substituted Allylic Acetate Derivatives [O] . Byeong-Seon Kim, Dr. Mahmud M. Hussain, Nusrah Hussain, -1

机译：钯催化的化学选择性烯丙基取代Suzuki-Miyaura交叉偶联和双功能2-B（pin）取代的乙酸乙酸烯丙酯衍生物的烯丙基形成
7. Raising the pKa Limit of “Soft” Nucleophiles in Palladium-Catalyzed Allylic Substitutions: Application of Diarylmethane Pronucleophiles [O] . Sheng-Chun Sha, Jiadi Zhang, Patrick J. Carroll, 2013

机译：培养钯催化烯丙基取代中“软”亲核试剂的PKA限制：在二芳基甲烷前核开剂的应用

DIASTEREOSELECTIVE SYNTHESIS OF VINYLMORPHOLINES BY PALLADIUM-CATALYZED TANDEM ALLYLIC SUBSTITUTIONS USING ENANTIOPURE AMINOALCOHOLS AS BIFUNCTIONAL NUCLEOPHILES

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