CRYSTALLIZATION AND STRUCTURE OF HEXAMERIC ACI-9-NITROFLUORENE-POTASSIUM CONTAINING A LIPOPHILICALLY WRAPPED POLYION AGGREGATE [K-6(CIRCLE-PLUS)(O-12)(CIRCLE-MINUS-6)]

摘要

Aci-9-nitrofluorene potassium salt crystallizes as a hexamer around a polyion aggregate [K-6(+)(O-12)(6)(-)] which in addition is solvated by one dioxane and two tetrahydrofuran molecules. The lipophilic skin {C77H72} limits the size of the thermodynamically favorable metal oxide cluster and provides a molecular self-organization principle for the crystallization of analogous compounds. [References: 19]