STEREOSELECTIVE SYNTHESIS OF ALPHA-SUBSTITUTED ULOSONIC ACIDS BY MAGNESIO-REFORMATSKY REACTIONS

Csuk R.; Krieger C.; Schroder C.

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STEREOSELECTIVE SYNTHESIS OF ALPHA-SUBSTITUTED ULOSONIC ACIDS BY MAGNESIO-REFORMATSKY REACTIONS

机译：镁-重整反应立体选择性合成α-取代的超声酸

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A new method of homologation of aldonolactones allowing the incorporation of propionate units with excellent chemo- and stereoselectivity is performed by the magnesium-graphite mediated reaction between Oppolzer sultam derived alpha-halogenated amides and an aldonolactone. (C) 1997 Elsevier Science Ltd. [References: 44]

机译：Oppolzer sultam衍生的α-卤代酰胺与Aldonolactone之间的镁-石墨介导的反应，是一种使Aldonolactones同源化的新方法，该方法可以使丙酸酯单元具有出色的化学和立体选择性。（C）1997 Elsevier Science Ltd. [参考：44]

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《Tetrahedron》 |1997年第38期|共14页
作者
Csuk R.; Krieger C.; Schroder C.;
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正文语种 eng
中图分类有机化学;
关键词
N-acetylneuraminic acid; Influenza-virus; Catalyzed-reactions; Carbonyl-compounds; Kdn; Aldonolactones; Sialidase; Analogs; Aldolase; Reagents;

机译：N-乙酰神经氨酸;流感病毒;催化反应;羰基化合物;Kdn;醛糖内酯;唾液酸酶;类似物;醛缩酶;试剂;

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专利

1. STEREOSELECTIVE SYNTHESIS OF ALPHA-SUBSTITUTED ULOSONIC ACIDS BY MAGNESIO-REFORMATSKY REACTIONS [J] . Csuk R., Krieger C., Schroder C. Tetrahedron . 1997,第38期

机译：镁-重整反应立体选择性合成α-取代的超声酸
2. FIRST MICHAEL ADDITION REACTION OF ALPHA-SUBSTITUTED N-DIPHENYLMETHYLENEGLYCINATE WITH ETHYL PROPIOLATE - SYNTHESIS OF ALPHA-SUBSTITUTED (E)-3,4-DEHYDROGLUTAMIC ACIDS [J] . Rubio A., Ezquerra J. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第32期

机译：α-取代的N-二苯甲基乙二酸乙二醇酯与丙酸乙酯的首次迈克尔加成反应-α-取代的（E）-3,4-脱水葡萄糖醛酸的合成
3. The stereoselective synthesis of alpha-substituted beta-amino secondary alcohols based on the proline-mediated, asymmetric, three-component Mannich reaction and its application to the formal total synthesis of nikkomycins B and B-x [J] . Hayashi Y, Urushima T, Shin M, Tetrahedron . 2005,第48期

机译：基于脯氨酸介导的不对称三组分曼尼希反应的α-取代的β-氨基仲醇的立体选择性合成及其在尼克霉素B和B-x的正式全合成中的应用
4. Stereoselective Synthesis of alpha-Allenols by Rhodium-Catalyzed Arylative Ring-Opening Reaction of Alkynyl Oxiranes with Arylboronic Acids [C] . Masahiko Shimada, Tomoya Miura, Masahiro Murakami Symposium on Organometallic Chemistry . 2007

机译：芳基催化芳基苯甲酸芳基苯甲酸芳基苯甲酸芳基 - 苯甲酸芳基苯甲酸苯酚的立体选择性合成
5. Exploration of alpha-Diazocarbonyl Compounds for Transition-Metal Catalyzed Carbon-Carbon Bond Formations. Development of Palladium-Catalyzed Stereoselective Synthesis of Trisubstituted Alkenes and the Synthesis of Quaternary alpha,alpha-Heterodiaryl Carboxylic Acids by Rhodium-Catalyzed Multi-Component Coupling Reactions. [D] . Tsoi, Yuk Tai. 2012

机译：探索用于过渡金属催化的碳-碳键形成的α-重氮羰基化合物。铑催化的多组分偶合反应在钯催化的立体选择性合成三取代的烯烃上的发展和季铵的α，α-杂二芳基羧酸的合成。
6. First and Stereoselective Synthesis of an α-(2→5)-LinkedDisaccharide of 3-Deoxy-d-manno-oct-2-ulosonic Acid (Kdo) [O] . Barbara Pokorny, Paul Kosma, * -1

机译：α-（2→5）链的第一和立体选择性合成3-Deoxy-d-manno-oct-2-ulosonic acid（Kdo）的二糖
7. First and Stereoselective Synthesis of an α-(2→5)-Linked Disaccharide of 3-Deoxy-d-manno-oct-2-ulosonic Acid (Kdo) [O] . Barbara Pokorny, Paul Kosma 2014

机译：α-（2→5） - 3-脱氧-D-MANNO-OCT-2-溃疡酸（KDO）的α-（2→5）的二糖的第一和立体选择合成

STEREOSELECTIVE SYNTHESIS OF ALPHA-SUBSTITUTED ULOSONIC ACIDS BY MAGNESIO-REFORMATSKY REACTIONS

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