MICROBIOLOGICAL TRANSFORMATIONS .36. PREPARATIVE SCALE SYNTHESIS OF CHIRAL THIOACETAL AND THIOKETAL SULFOXIDES USING WHOLE-CELL BIOTRANSFORMATIONS

Alphand V.; Colonna S.; Pasta P.; Furstoss R.; Gaggero N.

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MICROBIOLOGICAL TRANSFORMATIONS .36. PREPARATIVE SCALE SYNTHESIS OF CHIRAL THIOACETAL AND THIOKETAL SULFOXIDES USING WHOLE-CELL BIOTRANSFORMATIONS

机译：微生物转化.36。利用全细胞生物转化制备手性硫代缩醛和硫代缩酮的规模化合成

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This work describes the preparative scale enantioselective oxidation of some prochiral dithioacetals and dithioketals to their corresponding chiral monosulfoxides using whole-cell cultures of microorganisms. (C) 1997 Elsevier Science Ltd. [References: 85]

机译：这项工作描述了使用微生物的全细胞培养物，将一些前手性二硫缩醛和二硫缩酮制备成规模的对映选择性氧化为它们相应的手性单亚砜。（C）1997 Elsevier Science Ltd. [参考：85]

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《Tetrahedron》 |1997年第28期|共12页
作者
Alphand V.; Colonna S.; Pasta P.; Furstoss R.; Gaggero N.;
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正文语种 eng
中图分类有机化学;
关键词
Catalytic asymmetric oxidation; Helminthosporium species nrrl-4671; Flavin-containing monooxygenase; Benzyl methyl sulfoxides; Cyclohexanone monooxygenase; Enantioselective oxidation; Organic sulfides; Stereoselective synthesis; 1; 3-dithiane 1-oxides; Carbonyl-compounds;

机译：催化不对称氧化;蠕孢菌属物种nrrl-4671;含黄素的单加氧酶;苄基甲基亚砜;环己酮单加氧酶;对映选择性氧化;有机硫化物;立体选择性合成;1;3-二硫杂环丁烷1-氧化物;羰基化合物;

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1. MICROBIOLOGICAL TRANSFORMATIONS .36. PREPARATIVE SCALE SYNTHESIS OF CHIRAL THIOACETAL AND THIOKETAL SULFOXIDES USING WHOLE-CELL BIOTRANSFORMATIONS [J] . Alphand V., Colonna S., Pasta P., Tetrahedron . 1997,第28期

机译：微生物转化.36。利用全细胞生物转化制备手性硫代缩醛和硫代缩酮的规模化合成
2. Biotransformation of organic sulfides Part. 10. Formation of chiral ortho-and meta-substituted benzyl methyl sulfoxides by biotransformation using Helminthosporium species NRRL 4671 [J] . Herbert L. Holland, Frances M. Brown, Ali Kerridge, Journal of molecular catalysis, B. Enzymatic . 1999,第5期

机译：有机硫化物的生物转化10.使用蠕虫孢子菌种NRRL 4671通过生物转化形成手性邻位和间位取代的苄基甲基亚砜
3. Microbiological Transformations 57. Facile and Efficient Resin-Based in Situ SFPR Preparative-Scale Synthesis of an Enantiopure "Unexpected" Lactone Regioisomer via a Baeyer-Villiger Oxidation Process [J] . Iris Hilker, Maria C. Gutierrez, Veronique Alphand, Organic letters . 2004,第12期

机译：微生物转化57.通过Baeyer-Villiger氧化过程，对映纯的“意外”内酯区域异构体的高效，高效树脂基原位SFPR制备规模合成。
4. Biotransformations in Natural Product Synthesis -Efficient Access to Chiral Building Blocks [C] . Diana Sandkuhl, Thomas Fischer, Jorg Pietruszka European Symposium on Organic Chemistry . 2009

机译：自然产品综合的生物转化 - 对手性建筑块的效率接近
5. New methodologies for the asymmetric synthesis of alkaloids using chiral vinylic sulfoxides: I. An enantioselective synthesis of the aspidosperma skelton and II. A novel approach to pyrrolidines and pyrrolizidines. [D] . Rubio, Maria Belen. 2000

机译：使用手性乙烯基亚砜不对称合成生物碱的新方法：I.蛇蝎精子的对映选择性合成和II。吡咯烷和吡咯烷的新方法。
6. Whole-cell biotransformation systems for reduction of prochiral carbonyl compounds to chiral alcohol in Escherichia coli [O] . Bingjuan Li, Yuxia Li, Dongmei Bai, -1

机译：用于在大肠杆菌中将前手性羰基化合物还原为手性醇的全细胞生物转化系统
7. Carbonyl reductase identification and development of whole-cell biotransformation for highly efficient synthesis of ()-3,5-bis(trifluoromethyl)phenyl ethanol [O] . 2016

机译：羰基还原酶的鉴定和高效合成（）-3,5-双（三氟甲基）苯基乙醇的全细胞生物转化技术的开发
8. Application of Toluene Dioxygenase in the Synthesis of Acetylene-TerminatedResins (m-Hydroxy Phenylacetylene Biotransformation Project) [R] . Williams, M. G., Olson, P. E., Tautvydas, K. J., 1990

机译：甲苯双加氧酶在乙炔封端的合成中的应用（间羟基苯乙炔生物转化项目）

MICROBIOLOGICAL TRANSFORMATIONS .36. PREPARATIVE SCALE SYNTHESIS OF CHIRAL THIOACETAL AND THIOKETAL SULFOXIDES USING WHOLE-CELL BIOTRANSFORMATIONS

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