Encapsulation of Cationic Organometallic Guests by a Chiral Self-Assembled Supramolecular Cage:Enantioselective Binding,Dynamic Resolution,and Selective C-H Bond Activation

摘要

To utilize the chiral tetrahedral supramolecular cluster,Ga_4L_6 [L = 1,5-bis(2'-3'-dihydroxybenzamido)naphthalene],as a stereospecific reaction vessel in which to study the selective encapsulation and reactivity of mono-cationic organometallic guests.