首页> 外文期刊>Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry >Chiral discrimination processes by C9 carbamate derivatives of dihydroquinine: interaction mechanisms of diastereoisomeric 9-O-[(S)- or (R)-1-(1-naphthyl)ethylcarbamate]dihydroquinine and the two enantiomers of N-(3,5-dinitrobenzoyl)alanine methyl ester
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Chiral discrimination processes by C9 carbamate derivatives of dihydroquinine: interaction mechanisms of diastereoisomeric 9-O-[(S)- or (R)-1-(1-naphthyl)ethylcarbamate]dihydroquinine and the two enantiomers of N-(3,5-dinitrobenzoyl)alanine methyl ester

机译:二氢奎宁的C9氨基甲酸酯衍生物的手性鉴别过程:非对映异构体9-O-[(S)-或(R)-1-(1-萘基)乙基氨基甲酸酯]二氢奎宁与N-(3,5-的两个对映体的相互作用机理二硝基苯甲酰基)丙氨酸甲酯

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摘要

Computational and NMR investigations of diastereoisomeric aggregates arising from the interaction of 9-O-[(S)- or (R)-1-(1-naphthyl)ethylcarbamate]dihydroquinine and the two enantiomers of N-(3,5-dinitrobenzoyl)alanine methyl ester pointed out the origin of chiral discrimination phenomena occurring in CDCl3 solutions. (C) 2008 Elsevier Ltd. All rights reserved.
机译:由9-O-[(S)-或(R)-1-(1-萘基乙基氨基甲酸酯)二氢奎宁与N-(3,5-二硝基苯甲酰基)的两个对映异构体相互作用产生的非对映异构体聚集体的计算和NMR研究丙氨酸甲酯指出了在CDCl3溶液中发生手性识别现象的起源。 (C)2008 Elsevier Ltd.保留所有权利。

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