Asymmetric synthesis of a 3,4-substituted pyrrolidine by L-proline catalyzed direct enolexo aldolization

Kumar I; Bhide SR; Rode CV

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Asymmetric synthesis of a 3,4-substituted pyrrolidine by L-proline catalyzed direct enolexo aldolization

机译：L-脯氨酸催化的直接烯醇式醛醇缩合反应不对称合成3,4-取代的吡咯烷

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The asymmetric synthesis of a 3,4-substituted N-tosyl pyrrolidine has been achieved by using L-proline catalyzed 5-enolexo aldolization with high enantio and diastereoselectivity. (C) 2007 Published by Elsevier Ltd.

机译：通过使用具有高对映和非对映选择性的L-脯氨酸催化的5-烯醛缩醛醛缩合反应已实现了3,4-取代的N-甲苯磺酰基吡咯烷的不对称合成。（C）2007年由Elsevier Ltd.出版

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《Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry》 |2007年第10期|共7页
作者
Kumar I; Bhide SR; Rode CV;
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正文语种 eng
中图分类有机化学;
关键词
ALDOL REACTIONS; AMINO-ACIDS; ORGANOCATALYSIS; ALDEHYDES; KETONES;

机译：ALDOL反应;氨基酸;有机催化;醛;酮;

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1. Asymmetric synthesis of a 3,4-substituted pyrrolidine by L-proline catalyzed direct enolexo aldolization [J] . Kumar I, Bhide SR, Rode CV Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2007,第10期

机译：L-脯氨酸催化的直接烯醇式醛醇缩合反应不对称合成3,4-取代的吡咯烷
2. Kinetic resolution of 4-substituted- 3,4-dihydrocoumarins via Pd-catalyzed asymmetric allylic alkylation reaction: enantioselective synthesis of trans- 3,4-disubstituted-3,4-dihydrocoumarins [J] . Xiao-Hui Li, Ping Fang, Di Chen Organic Chemistry Frontiers . 2014,第8期

机译：通过Pd催化的不对称烯丙基烷基化反应动力学拆分4-取代的3,4-二氢香豆素：对映选择性合成反式3,4-二取代的3,4-二氢香豆素
3. ASYMMETRIC NITROALKENE [4+2] CYCLOADDITIONS - ENANTIOSELECTIVE SYNTHESIS OF 3-SUBSTITUTED AND 3,4-DISUBSTITUTED PYRROLIDINES [J] . Denmark SE., Marcin LR. The Journal of Organic Chemistry . 1995,第10期

机译：不对称硝基烯烃[4 + 2]循环条件-3取代和3,4-取代吡咯二烯的对映选择性合成
4. Asymmetric Synthesis of 3,4-Dihydrocoumarins by the Rhodium-Catalyzed Reaction of 3-(2-Hydroxyphenyl)cyclobutanones [C] . Masanori Shigeno, Takanori Matsuda, Masahiro Murakami Symposium on Organometallic Chemistry . 2007

机译：通过3-（2-羟基苯基）环丁酮的铑催化反应的3,4-二氢脲ourins的不对称合成
5. Part I. Asymmetric organocatalysis: (1) Direct enantioselective organocatalytic hydroxymethylation of aldehydes catalyzed by alpha,alpha-diphenylprolinol trimethylsilyl ether: Application in the formal synthesis of (-)-Rasfonin; (2) Synthesis of a novel bicyclic secondary amine organocatalyst: Application to the direct enantioselective organocatalytic hydroxymethylation of aldehydes. Part II. Asymmetric synthesis of bicyclic analogues of the anti-osteoporotic drug risedronate. [D] . Miller, John Robert. 2010

机译：第一部分，不对称有机催化：（1）α，α-二苯基脯氨醇三甲基甲硅烷基醚催化的醛的直接对映选择性有机催化羟甲基化：在（-）-Rasfonin的正式合成中的应用；（2）新型双环仲胺有机催化剂的合成：应用于醛的直接对映选择性有机催化羟甲基化。第二部分抗骨质疏松药物Risedronate的双环类似物的不对称合成。
6. Asymmetric Synthesis of Polyfunctionalized Pyrrolidines from Sulfinimine-Derived Pyrrolidine 2-Phosphonates. Synthesis of Pyrrolidine 225C [O] . Franklin A. Davis, He Xu, Yongzhong Wu, -1

机译：从亚磺胺衍生的吡咯烷2-膦酸酯不对称合成多官能化吡咯烷。吡咯烷225C的合成
7. Phosphoramidite Gold(I)-Catalyzed Diastereo- and Enantioselective Synthesis of 3,4-Substituted Pyrrolidines [O] . González Ana Z., Benitez Diego, Tkatchouk Ekaterina, 2011

机译：亚磷酰胺金（I）催化的3,4-取代吡咯烷的非对映和对映选择性合成

Asymmetric synthesis of a 3,4-substituted pyrrolidine by L-proline catalyzed direct enolexo aldolization

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