Synthesis and studies of 6,6 '-BINAP derivatives for the heterogeneous asymmetric hydrogenation of methyl acetoacetate

Saluzzo C.; Lamouille T.; Le Guyader F.; Lemaire M.

首页> 外文期刊>Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry >Synthesis and studies of 6,6 '-BINAP derivatives for the heterogeneous asymmetric hydrogenation of methyl acetoacetate

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Synthesis and studies of 6,6 '-BINAP derivatives for the heterogeneous asymmetric hydrogenation of methyl acetoacetate

机译：乙酰乙酸甲酯非均相不对称氢化反应的6,6'-BINAP衍生物的合成与研究

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New BINAP derivatives (polyamide, polyureas or ureas) were synthesized and employed in the ruthenium-catalyzed asymmetric heterogeneous hydrogenation of methyl acetoacetate. Enantiomeric excesses in the range 48-100% were observed. Furthermore, the most efficient have been recovered and the recycled catalysts were shown to maintain their efficiency in subsequent reactions. (C) 2002 Elsevier Science Ltd. All rights reserved. [References: 24]

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《Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry》 |2002年第11期|共6页
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Saluzzo C.; Lamouille T.; Le Guyader F.; Lemaire M.;
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1. Synthesis and studies of 6,6 '-BINAP derivatives for the heterogeneous asymmetric hydrogenation of methyl acetoacetate [J] . Saluzzo C., Lamouille T., Le Guyader F., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2002,第11期

机译：乙酰乙酸甲酯非均相不对称氢化反应的6,6'-BINAP衍生物的合成与研究
2. Ru coordinated with BINAP in knitting aryl network polymers for heterogeneous asymmetric hydrogenation of methyl acetoacetate [J] . Tao Wang, Yuan Lyu, Xingkun Chen, RSC Advances . 2016,第34期

机译：Ru配位用Binap进行编织芳基网络聚合物，用于乙酰乙酸甲酯的非均相不对称氢化
3. Enhanced Enantioselectivity Achieved at Low Hydrogen Pressure for the Asymmetric Hydrogenation of Methyl Acetoacetate over a Tartaric Acid NaBr-Modified Raney Nickel Catalyst: A Kinetic Study [J] . Choliq Azka Azkiya, Nakae Rio, Watanabe Mariko, Bulletin of the Chemical Society of Japan . 2019,第7期

机译：在低氢气压力下实现的增强映射性，用于在酒石酸Nabr改性的Raney镍催化剂上进行乙酰乙酸甲酯的不对称氢化：动力学研究
4. Synthesis of Dendritic BINAP Ligands and Their Application in Asymmetric Hydrogenation [C] . Qing-Hua Fan, Fu Xi International symposium for Chinese organic chemists . 2000

机译：树突式Binap配体的合成及其在不对称氢化中的应用
5. Part One. Synthesis of optically active tryptophan derivatives with potential activity as indoleamine 2,3-dioxygenase inhibitors: An approach via asymmetric catalytic hydrogenation. Part Two. Design, synthesis and pharmacology of selective ligands for alpha1-containing GABA(A)/benzodiazepine receptor subtypes: SAR studies of beta-carbolines at positions -3 and -6 and their corresponding bivalent ligands. Part Three. First enantiospecific total synthesis of the important biogenetic intermediates, (+)-polyneuridine and (+)-polyneuridine aldehyde, as well as 16-epi-vellosimine and macusine A. [D] . Yin, Wenyuan. 2007

机译：第一部分。具有吲哚胺2,3-二加氧酶抑制剂潜在活性的旋光色氨酸衍生物的合成：一种通过不对称催化氢化的方法。第二部分。含α1的GABA（A）/苯并二氮杂receptor受体亚型的选择性配体的设计，合成和药理作用：位于-3和-6位的β-咔啉及其相应的二价配体的SAR研究。第三部分。重要生物遗传中间体，（+）-聚神经氨酸和（+）-聚神经氨酸醛，以及16-表-维西辛和Macusine A的首次对映体全合成。
6. Asymmetric Synthesis of Dipropionate Derivatives through Catalytic Hydrogenation of Enantioenriched E-Ketene Heterodimers [O] . Shi Chen, Mukulesh Mondal, Ahmad A. Ibrahim, -1

机译：对映体富集的烯酮异二聚体的催化加氢不对称合成二丙酸酯衍生物
7. Asymmetric Hydrogenation of Ketones with Ruthenium Complexes of rac- and Enantiopure (S,S)-1,2-Bis((diphenylphosphino)methyl)cyclohexane: Comparative Study with rac- and (R)-BINAP [O] . -1

机译：酮与甲烯酮复合物的非对称氢化 - 甲炔醇（S，S，S，S）-1,2-双（（二苯基膦基）甲基）环己烷：与Rac-和（R）-Binap的比较研究
8. Theoretical Prediction of the Heats of Formation, Densities and Relative Sensitivities, and/or Synthetic Approaches Toward the Synthesis of High Energy Dense Materials (HEDMs): 3,5-Dinitro-1,3,5-Oxadiazinane, Bis-Adjacent RDX, Bis-Adjacent HMX, 4,4',6,6'-Tetranitro-1,1'-Bis(N-oxide)-5,5',6,6'-4H,4'H-5,5'-Bisimidazo Oxadiazole, and the Open-Cage Derivative of CL-20. [R] . Byrd, E. F., Sabatini, J. J. 2015

机译：形成热，密度和相对灵敏度的理论预测，和/或合成高能量密集材料（HEDms）的合成方法：3,5-二硝基-1,3,5-恶二唑烷，双相邻RDX，Bis - 相邻的HmX，4,4'，6,6'-四硝基-1,1'-双（N-氧化物）-5,5'，6,6'-4H，4'H-5,5'-双咪唑恶二唑和CL-20的开笼衍生物。

Synthesis and studies of 6,6 '-BINAP derivatives for the heterogeneous asymmetric hydrogenation of methyl acetoacetate

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