Novel efficient bifunctional calixarene thiourea organocatalysts: synthesis and application in the direct enantioselective aldol reactions

Genc Hayriye Nevin; Sirit Abdulkadir

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Novel efficient bifunctional calixarene thiourea organocatalysts: synthesis and application in the direct enantioselective aldol reactions

机译：新型有效的双功能杯芳烃硫脲有机催化剂：在直接对映选择性羟醛反应中的合成与应用

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Novel efficient bifunctional calixarene thiourea organocatalysts have been designed as efficient organocatalysts for direct asymmetric aldol reactions between acetone and aromatic aldehydes. The reactions generated the corresponding products in satisfactory isolated yields (up to 96%) and with excellent enantiomeric excesses (up to 99%) in the presence of catalyst (10 mol %). (C) 2016 Elsevier Ltd. All rights reserved.

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《Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry》 |2016年第5期|共7页
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Genc Hayriye Nevin; Sirit Abdulkadir;
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中图分类有机化学;
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1. Novel efficient bifunctional calixarene thiourea organocatalysts: synthesis and application in the direct enantioselective aldol reactions [J] . Genc Hayriye Nevin, Sirit Abdulkadir Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2016,第4a5期

机译：新型有效的双功能杯芳烃硫脲有机催化剂：在直接对映选择性羟醛反应中的合成与应用
2. One-step, efficient synthesis of combined threonine-surfactant organocatalysts for the highly enantioselective direct aldol reactions of cyclic ketones with aromatic aldehydes in the presence of water [J] . Wu C., Fu X., Ma X., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2010,第20期

机译：一步法高效合成苏氨酸表面活性剂有机催化剂，用于在水存在下环状酮与芳族醛的高度对映选择性直接羟醛反应
3. Recyclable polyvinyl chloride-supported pyrrolidine-thiourea as a bifunctional organocatalyst for direct asymmetric aldol reaction in aqueous medium [J] . Li J., Yang G., Cui Y. Journal of Applied Polymer Science . 2011,第3期

机译：可回收的聚氯乙烯负载的吡咯烷-硫脲作为双官能有机催化剂，可在水性介质中直接进行不对称羟醛反应
4. Enantioselective Mannich Reaction of α-Fluorinated β-Ketoesters Catalyzed by a Novel Bifunctional Thiourea Catalyst [C] . Jacek Kwiatkowski, Han Xiao, Yixin Lu European Symposium on Organic Chemistry . 2009

机译：新型双官能硫脲催化剂催化的α-氟化β-酮间酯的对映选择性曼尼希反应
5. Part I. Asymmetric organocatalysis: (1) Direct enantioselective organocatalytic hydroxymethylation of aldehydes catalyzed by alpha,alpha-diphenylprolinol trimethylsilyl ether: Application in the formal synthesis of (-)-Rasfonin; (2) Synthesis of a novel bicyclic secondary amine organocatalyst: Application to the direct enantioselective organocatalytic hydroxymethylation of aldehydes. Part II. Asymmetric synthesis of bicyclic analogues of the anti-osteoporotic drug risedronate. [D] . Miller, John Robert. 2010

机译：第一部分，不对称有机催化：（1）α，α-二苯基脯氨醇三甲基甲硅烷基醚催化的醛的直接对映选择性有机催化羟甲基化：在（-）-Rasfonin的正式合成中的应用；（2）新型双环仲胺有机催化剂的合成：应用于醛的直接对映选择性有机催化羟甲基化。第二部分抗骨质疏松药物Risedronate的双环类似物的不对称合成。
6. Highly Enantioselective Three-Component Direct Mannich Reactions of Unfunctionalized Ketones Catalyzed by Bifunctional Organocatalysts [O] . Qunsheng Guo, John Cong-Gui Zhao -1

机译：非官能化酮催化的高对映三组分直接曼尼希反应的双功能有机催化剂
7. N-Tosyl-(Sa)-binam-L-prolinamide as highly efficient bifunctional organocatalyst for the general enantioselective solvent-free aldol reaction [O] . Guillena, Gabriela, Nájera, Carmen, Viózquez Cámara, Santiago Fidel 2008

机译：N-Tosyl-（Sa）-binam-L-脯氨酰胺作为高效的双功能有机催化剂，用于一般对映选择性无溶剂的羟醛反应

Novel efficient bifunctional calixarene thiourea organocatalysts: synthesis and application in the direct enantioselective aldol reactions

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