A New Class of Chiral Lewis Acid Catalysts for Highly Enantioselective Hetero-Diels-Alder Reactions: Exceptionally High Turnover Numbers from Dirhodium(II) Carboxamidates

M. P. Doyle; I. M. Phillips; W. Hu; Huw M. L. Davies

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A New Class of Chiral Lewis Acid Catalysts for Highly Enantioselective Hetero-Diels-Alder Reactions: Exceptionally High Turnover Numbers from Dirhodium(II) Carboxamidates

机译：一类新型的手性路易斯酸催化剂，用于高度对映选择性杂-Diels-Alder反应：氨基甲酸二（二）吡啶鎓盐的异常高周转数

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摘要

To develop new chiral Lewis acids capable of high-turnover numbers in the hetero-Diels-Alder reaction.

机译：为了开发能够在杂Diels-Alder反应中具有高周转数的新手性路易斯酸。

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《Chemtracts》 |2001年第11期|共4页
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M. P. Doyle; I. M. Phillips; W. Hu; Huw M. L. Davies;
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1. A New Class of Chiral Lewis Acid Catalysts for Highly Enantioselective Hetero-Diels-Alder Reactions: Exceptionally High Turnover Numbers from Dirhodium(II) Carboxamidates [J] . M. P. Doyle, I. M. Phillips, W. Hu, Chemtracts . 2001,第11期

机译：一类新型的手性路易斯酸催化剂，用于高度对映选择性杂-Diels-Alder反应：氨基甲酸二（二）吡啶鎓盐的异常高周转数
2. Highly enantioselective hetero-Diels-Alder reactions between Rawal's diene and aldehydes catalyzed by chiral dirhodium(II) carboxamidates [J] . Yudai Watanabe, Takuya Washio, Naoyuki Shimada, Chemical Communications . 2009,第47期

机译：手性氨基羧酸二铵催化拉瓦尔的二烯与醛之间的高度对映选择性杂Diels-Alder反应
3. Chiral rare earth organophosphates as homogeneous Lewis acid catalysts for the highly enantioselective hetero-Diels-Alder reactions [J] . Furuno H., Hayano T., Kambara T., Tetrahedron . 2003,第52期

机译：手性稀土有机磷酸盐作为均相路易斯酸催化剂，用于高度对映选择性杂-Diels-Alder反应
4. A Highly Enantioselective Hetero-Diels-Alder Reaction of Aldehydes withDanishefsky's Diene Catalyed by Chiral Titanium (Ⅳ) H8-Binolcomplexes [C] . (missing) International symposium on green chemistry in China . 2002

机译：一种高度映选择性的异源二氧化醛醛与手性钛（Ⅵ）H8-Binolcomplecces的醛催化的醛催化反应
5. Dirhodium(II) carboxamidate catalysts as Lewis acids for the hetero-Diels-Alder reaction. [D] . Valenzuela, Marcela V. 2004

机译：羧酸氨基甲酸二铱（II）催化剂作为路易斯酸用于杂Diels-Alder反应。
6. Asymmetric Catalysis Special Feature Part I: Air-stable storable and highly efficient chiral zirconium catalysts for enantioselective Mannich-type aza Diels–Alder aldol and hetero Diels–Alder reactions [O] . Shū Kobayashi, Masaharu Ueno, Susumu Saito, 2004

机译：不对称催化的特殊功能（第一部分）：对映选择性曼尼希型氮杂Diels–AlderAldol和杂Diels–Alder反应的空气稳定可储存且高效的手性锆催化剂
7. Dirhodium(II) Tetrakis[N-benzene-fused Phthaloyl-(S)-piperidinonate] as a Chiral Lewis Acid: Catalytic Enantioselective Aldol Reactions of Acetate-derived Silylketene Acetals and Aldehydes [O] . Washio, Takuya, Nakamura, Seiichi, Anada, Masahiro, 2005

机译：作为手性路易斯酸的四（D）铑（II）四[N-苯稠合的邻苯二甲酰基-（S）-哌啶子酸酯]：乙酸酯衍生的甲硅烷基烯酮缩醛和醛的催化对映选择性醛醇缩合反应

A New Class of Chiral Lewis Acid Catalysts for Highly Enantioselective Hetero-Diels-Alder Reactions: Exceptionally High Turnover Numbers from Dirhodium(II) Carboxamidates

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