The applicability of ozone as a digestion agent in voltammetric trace metal analysis of water samples was investigated. It was shown that ozone efficiently destroys dissolved organic matter, causing a significant decrease of the concentration of surface active substances in the sample, thus enabling voltammetric measurements. Ozonolysis times of 30 and 60 min were sufficient for the treatment of river water and biologically treated wastewater samples, depending on their organic load, prior to voltammetric determination of copper using a solid gold electrode.
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