From high-spin organic molecules to organic polymers with magnetic ordering

摘要

This concept paper outlines the design of the first pi-conjugated organic polymer with magnetic ordering. This rational. "bottom-up" macromolecular design is based on synthesis and study of polyarylmethyl polyradicals with increasing number of exchange-coupled unpaired electron spins. The prospects for attaining organic polymer magnets with stability Lit ambient temperature and/or higher magnetic ordering temperatures will be discussed. [References: 59]