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首页> 外文期刊>Polymer science, Series B. Rapid communications reviews >Phase Transitions of Liquid Crystalline Cyanoethyl Cellulose Solutions under Static Conditions and in Shear Field
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Phase Transitions of Liquid Crystalline Cyanoethyl Cellulose Solutions under Static Conditions and in Shear Field

机译:静态和剪切场下液晶氰乙基纤维素溶液的相变

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Phase transitions in the systems cyanoethyl cellulose-DMF, cyanoethyl cellulose-DMAA, and cyanoethyl cellulose-(trifluoroacetic acid + methylene chloride) were studied by means of the cloud-point and polarization microscopy techniques, as well as with a photoelectric polarization unit and a modified plasti-corder. It was shown that the LC phase appears at higher concentrations and lower temperatures as the polarity of solvent molecules increases. The shear deformation of cyanoethyl cellulose solutions in DMF and DMAA results in the expansion of the temperature-concentration region of existence of the LC phase. The effect of shear field on phase transitions in cyanoethyl cellulose solutions is nonmonotonic in character.
机译:通过浊点和偏振显微镜技术以及光电偏振单元和红外光谱仪研究了氰乙基纤维素-DMF,氰乙基纤维素-DMAA和氰乙基纤维素-(三氟乙酸+二氯甲烷)体系中的相变。改良质体。结果表明,随着溶剂分子极性的增加,LC相出现在较高的浓度和较低的温度下。氰乙基纤维素溶液在DMF和DMAA中的剪切变形导致存在LC相的温度集中区域扩大。剪切场对氰乙基纤维素溶液中相变的影响是非单调的。

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