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Flexural and impact properties of oil palm empty fruit bunch (EFB)-polypropylene composites - the effect of maleic anhydride chemical modification of EFB

机译:油棕空果束(EFB)-聚丙烯复合材料的弯曲和冲击性能-EFB的马来酸酐化学改性的作用

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摘要

This study focused on the effect of chemical modification of oil palm empty fruit bunch (EFB) filler on the flexural and impact properties of EFB-filled polypropylene (PP) composites. EFB filler has been chemically modified with maleic anhydride (MAH). The modification involved the reaction of EFB and MAH (dissolved in dimethylformamide) at 90degreesC. The composites with MAH-treated EFB showed higher flexural and impact strength than those with untreated EFB. The modification had significantly improved the flexural modulus and toughness of the composites. This may be attributed to the enhanced adhesion between the MAH-treated EFB and PP matrix, as shown in the scanning electron microscopy (SEM) study. Fourier Transform Infra-Red analysis (FTIR) showed evidence of C=C and C=O groups from MAH at 1630cm(-1) and 1730cm(-1), respectively. The analysis also showed a reduction of absorption at 1630cm(-1) for MAH modified EFB-PP composites which indicated the reaction of C=C from MAH with PP. (C) 2002 Elsevier Science Ltd. All rights reserved. [References: 10]
机译:这项研究集中于油棕空果束(EFB)填料的化学改性对EFB填充聚丙烯(PP)复合材料的弯曲和冲击性能的影响。 EFB填料已用马来酸酐(MAH)化学改性。所述修饰涉及EFB和MAH(溶于二甲基甲酰胺中)在90℃下的反应。 MAH处理的EFB的复合材料比未处理的EFB的复合材料显示出更高的弯曲强度和冲击强度。改性显着改善了复合材料的弯曲模量和韧性。如扫描电子显微镜(SEM)研究所示,这可能归因于MAH处理的EFB和PP基体之间增强的附着力。傅立叶变换红外分析(FTIR)显示分别来自MAH的C = C和C = O组的证据,分别位于1630cm(-1)和1730cm(-1)。分析还显示MAH改性的EFB-PP复合材料在1630cm(-1)处的吸收减少,这表明MAH与PP发生C = C反应。 (C)2002 Elsevier ScienceLtd。保留所有权利。 [参考:10]

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