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首页> 外文期刊>Chemistry: A European journal >Strategies to Stabilize New Members of the (A_3A'BO_6)_alpha(A_3B_3O_9)_beta Homologous series in the Sr-Rh-O System: Structure of the One-Dimensional (alpha = 3, beta = 2) [Sr_10(Sr_0.5Rh_1.5)_TP(Rh_6)_Oh]O_24 Oxide
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Strategies to Stabilize New Members of the (A_3A'BO_6)_alpha(A_3B_3O_9)_beta Homologous series in the Sr-Rh-O System: Structure of the One-Dimensional (alpha = 3, beta = 2) [Sr_10(Sr_0.5Rh_1.5)_TP(Rh_6)_Oh]O_24 Oxide

机译:稳定(A_3A'BO_6)_alpha(A_3B_3O_9)_beta Sr-Rh-O系统中同源序列的新成员的策略:一维结构(alpha = 3,beta = 2)[Sr_10(Sr_0.5Rh_1。 5)_TP(Rh_6)_Oh] O_24氧化物

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摘要

The (alpha = 3, beta = 2) member of the (A_3A'BO_6)_alpha(A_3B_3O_9)_beta homologous series has been sabilised in the Sr-Rh-O system for a [Sr_10(Sr_0.5Rh_1.5)_TP(Rh_6)_Oh]O_24 composition. The structural characterisation has been performed by powder X-ray and electron diffraction measurements and high-resolution electron microscopy. In this structure, three face-sharing [RhO_6] octahedra linked by one [Rh/SrO_6] trigonal prism comprise the infinite one-dimensional chain that runs parallel to the c axis of a trigonal unit cell (P3c1), with parameters a = 9.6411(1) and c = 21.2440(4) A.
机译:(A_3A'BO_6)_alpha(A_3B_3O_9)_beta同源序列的(alpha = 3,beta = 2)成员已经在Sr-Rh-O系统中稳定用于[Sr_10(Sr_0.5Rh_1.5)_TP(Rh_6) )_Oh] O_24组成。通过粉末X射线和电子衍射测量以及高分辨率电子显微镜来进行结构表征。在此结构中,由一个[Rh / SrO_6]三角棱镜链接的三个面部共享[RhO_6]八面体组成平行于三角形晶胞(P3c1)c轴的无限一维链,参数a = 9.6411 (1)和c = 21.2440(4)A。

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