Enantio- and Diastereoselective Iodocyclopropanation of Allylic Alcohols by Using a Substituted Zinc Carbenoid

Louis-Philippe B. Beaulieu; Lucie E. Zimmer; AndreB. Charette

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Enantio- and Diastereoselective Iodocyclopropanation of Allylic Alcohols by Using a Substituted Zinc Carbenoid

机译：使用取代的类锌锌烯醇对映体和非对映体选择性碘环丙烷化

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In addition to being present in several bioactive natural products,[1] 1,2,3-trisubstituted cyclopropanes embed significant structural complexity that has prompted their use as peptidomimetics,[2] and as substrates for various organic and organometallic reactions

机译：除存在于几种生物活性天然产物中外，[1] 1,2,3-三取代的环丙烷还具有显着的结构复杂性，促使其用作拟肽模拟物[2]以及用作各种有机和有机金属反应的底物

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《Chemistry: A European journal》 |2009年第44期|共4页
作者
Louis-Philippe B. Beaulieu; Lucie E. Zimmer; AndreB. Charette;
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正文语种 eng
中图分类应用化学;
关键词
Diastereoselective; Carbenoid; synthesis;

机译：非对映选择性;类胡萝卜素;合成;

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1. Enantio- and Diastereoselective Iodocyclopropanation of Allylic Alcohols by Using a Substituted Zinc Carbenoid [J] . Louis-Philippe B. Beaulieu, Lucie E. Zimmer, AndreB. Charette Chemistry: A European journal . 2009,第44期

机译：使用取代的类锌锌烯醇对映体和非对映体选择性碘环丙烷化
2. Diastereoselective Fluorocyclopropanation of Chiral Allylic Alcohols Using an alpha-Fluoroiodomethylzinc Carbenoid [J] . Navuluri Chandrasekhar, Charette Andre B. Organic letters . 2015,第17期

机译：使用α-氟代碘代甲基锌类胡萝卜素的手性烯丙醇的非对映选择性氟环丙烷化
3. Synthesis of fluorocyclopropanes via the enantioselective cyclopropanation of fluoro-substituted allylic alcohols using zinc carbenoids [J] . La?titia Delion, Thomas Poisson, Philippe Jubault, Canadian Journal of Chemistry . 2020,第9期

机译：使用锌羧酸锌通过荧光烯丙基醇的映选择性环丙烷合成氟环丙烷
4. Organocatalytic Enantio- and Diastereoselective Acetalization of δ-Oxoenones via Cyanohydrin Formation [C] . Akira Matsumoto, Keisuke Asano, Seijiro Matsubara 日本化学会春季年会講演予稿集 . 2018

机译：通过氰醇形成的δ-氧代酮的有机催化和非对映选择性缩醛化
5. Cyclopropanation mediated by zinc carbenoid: The highly enantio- and diastereoselective one-pot approach [D] . Kim, Hun Young 2008

机译：类胡萝卜素锌介导的环丙烷化：高度对映和非对映选择性一锅法
6. Cation Control of Diastereoselectivity in Iridium-Catalyzed Allylic Substitutions. Formation of Enantioenriched Tertiary Alcohols and Thioethers by Allylation of 5H-Oxazol-4-ones and 5H-Thiazol-4-ones [O] . Wenyong Chen, John F. Hartwig -1

机译：在铱催化的烯丙基取代基中非对映选择性的阳离子控制。通过5H-Oxazol-4-one和5H-Thiazol-4-one的烯丙基化形成对映体丰富的叔醇和硫醚
7. Highly Enantio- and Diastereoselective One-Pot Synthesis of Acyclic Epoxy Alcohols and Allylic Epoxy Alcohols [O] . -1

机译：高肾上腺素和非对抗的一罐合成无环环氧醇和烯丙基环氧醇
8. A General Route to Terminally Substituted Allylic Derivatives of Silicon and Tin. Preparation of Allylic Lithium Reagents. [R] . Seyferth, D., Wursthorn, K. R., Mammarella, R. E. 1977

机译：硅和锡末端取代烯丙基衍生物的一般途径。烯丙基锂试剂的制备。

Enantio- and Diastereoselective Iodocyclopropanation of Allylic Alcohols by Using a Substituted Zinc Carbenoid

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