Development of palladium-carbene catalysts for telomerization and dimerization of 1,3-dienes: From basic research to industrial applications

Clement ND; Routaboul L; Grotevendt A; Jackstell R; Beller M

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Development of palladium-carbene catalysts for telomerization and dimerization of 1,3-dienes: From basic research to industrial applications

机译：钯-卡宾催化剂用于1,3-二烯的端粒化和二聚化的开发：从基础研究到工业应用

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The following account summarises recent developments in the area of palladium-catalysed telomerisation and dimerisation reactions of 1,3-dienes. The most active types of catalyst, palladium-carbene complexes, were tested in pilot plant and proved to be industrially viable.

机译：以下内容总结了钯催化1,3-二烯的端粒化和二聚反应领域的最新进展。在中试工厂中测试了活性最高的催化剂钯-卡宾络合物，并证明其在工业上可行。

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《Chemistry: A European journal》 |2008年第25期|共13页
作者
Clement ND; Routaboul L; Grotevendt A; Jackstell R; Beller M;
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正文语种 eng
中图分类化学;
关键词
dimerization; green chemistry; N-heterocyclic carbenes; palladium; telomerization; N-HETEROCYCLIC CARBENES; CROSS-COUPLING REACTIONS; TEMPERATURE IONIC LIQUIDS; ARYL CHLORIDES; OLEFIN METATHESIS; (ETA-1; ETA-3-OCTADIENEDIYL)PALLADIUM COMPLEXES; DIENE OLIGOMERIZATION; HOMOGENEOUS CATALYSIS; EFFICIENT CATALYSTS; PD(II) COMPLEXES;

机译：二聚;绿色化学;N-杂环卡宾;钯;端粒化;N-杂环碳烯;交叉偶联反应;温度离子液体;芳基氯;烯烃分解;（ETA-1;ETA-3-己二烯二基）钯络合物;均相催化;高效催化剂;PD（II）络合物;

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1. Development of palladium-carbene catalysts for telomerization and dimerization of 1,3-dienes: From basic research to industrial applications [J] . Clement ND, Routaboul L, Grotevendt A, Chemistry: A European journal . 2008,第25期

机译：钯-卡宾催化剂用于1,3-二烯的端粒化和二聚化的开发：从基础研究到工业应用
2. Efficient and Selective Telomerization of 1,3-Butadiene with Diols Catalyzed by Palladium-Carbene Complexes [J] . Grotevendt A, Jackstell R, Michalik D, ChemSusChem . 2009,第1期

机译：钯-碳配合物催化的1，3-丁二烯与二醇的高效选择性端聚
3. Efficient and Selective Telomerization of 1,3-Butadiene with Diols Catalyzed by Palladium-Carbene Complexes [J] . Grotevendt Anne, Jackstell Ralf, Michalik Dirk, ChemSusChem . 2009,第1期

机译：用钯 - 卡宾配合物催化的二醇的高效和选择性端粒化1,3-丁二烯
4. Neodymium 3-isopropoxide/methylaluminoxane/tert-butyl chloride catalyst for 1,3-diene polymerization [C] . DONG Wei-min Symposium of International Rubber Conference vol.A; 20040921-25; Beijing(CN) . 2004

机译：3-异丙氧基钕/甲基铝氧烷/叔丁基氯催化剂用于1,3-二烯聚合
5. Discovery and development of 3,3,3-trichloropropyl-1-triphenylphosphonium chloride: A reagent for synthesis of Z-1,3-enynes, Z,Z-1-chloro-1,3-dienes and 1,3-diynes [D] . Karatholuvhu, Maheswaran S. 2006

机译：3,3,3-三氯丙基-1-三苯基氯化chloride的发现与开发：用于合成Z-1,3-烯，Z，Z-1-氯-1,3-二烯和1,3-二炔的试剂
6. Fifty Years of Hydrosilylation in Polymer Science: A Review of Current Trends of Low-Cost Transition-Metal and Metal-Free Catalysts Non-Thermally Triggered Hydrosilylation Reactions and Industrial Applications [O] . Robin J. Hofmann, Matea Vlatković, Frank Wiesbrock 2017

机译：高分子科学中的氢化硅烷化五十年：低成本过渡金属和无金属催化剂非热引发的氢化硅烷化反应和工业应用的当前趋势的回顾
7. An industrially viable catalyst system for palladium-catalyzed telomerizations of 1,3-butadiene with alcohols [O] . Jackstell R, Harkal S, Jiao HJ, 2004

机译：用于钯催化的1,3-丁二烯与醇的端粒化的工业上可行的催化剂体系

Development of palladium-carbene catalysts for telomerization and dimerization of 1,3-dienes: From basic research to industrial applications

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