Simultaneous preconcentration of Cu(II), Cd(II) and Mn(II) on silica-polyethylene glycol and determination by flame atomic absorption spectrometry

摘要

A simultaneous solid phase extraction procedure for enrichment of Cu(II), Cd(II) and Mn(II) has been developed. The method is based on adsorption of Cu(II), Cd(II) and Mn(II) ions on polyethylene glycol-silica gel pre-conditioned with acetate buffer (pH 5.5). The adsorbed metal ions are eluted with nitric acid (1 mol L~(-1)) and determined by flame atomic absorption spectrometry. The calibration graph was linear in the range of 2-140 ng mL -1 for Cu(II), 1-40 ng mL~(-1) for Cd(II) and 4-100 ng mL~(-1) for Mn(II). The limits of detection were 0.66, 0.33 and 1.20 ng mL~(-1) for Cu(II), Cd(II) and Mn(II), respectively.