Solid-state selenium-77 NMR

摘要

Since its initial discovery by Berzelius in 1818, selenium has steadily been incorporated in nearly all areas of chemistry. While the early chemistry involving selenium was predominately inorganic in nature [1], the development of organoselenium chemistry in the 1970s [2–4] paved the way for many of the studies probing the suspected importance of selenium in biological systems over the next 30 years [5]. With selenium as an essential nutrient in mammalian systems firmly solidified [6–8], attention has returned to selenium within inorganic systems particularly with regard to materials chemistry.