Application of the LSER Method for Investigation of Intermolecular Interactions of Porous Polymer Surface with Organic Molecules

摘要

The contributions of intermolecular interactions into the molar change of free energy -ΔF of sorption on the surface of porous polymers of various natures were studied by the linear solvation-energy relationship (LSER) method. It was shown that a high correlation coefficient does not ensure reliability of the results obtained. The applicability of the LSER equations for investigation of the polarity of polymer sorbents was analyzed.