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Effect of yttria(Y2O3) coating for high temperature oxidation resistance of 9Cr-1Mo steel

机译:氧化钇(Y2O3)涂层对9Cr-1Mo钢耐高温氧化性能的影响

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This paper investigates the effect of yttria (Y2O3) coating on high temperature oxidation behaviour of low alloy 9 Cr-1Mo steel. The superficial coating is Y2O3 was prepared for experimental investigation. The isothermal corrosion study of uncoated and coated specimens was carried out in air oxidation environment at 973 K for 8 h. The corrosion rate and reaction kinetics were studied and the post corroded scales were characterized in SEM, EDS and XRD. The results clearly indicate that Y2O3 coated specimen improves the high temperature oxidation resistance than uncoated specimens. The improvement of oxidation resistance in presence of Y2O3 coating can be attributed to the changed mechanism of scale growth from outer cation migration to inner anion migration and enhancement of scale adhesion with the substrate. Further, enhancement of scale adhesion with the substrate in case of Y2O3 coating also improves the oxidation resistance. The detail mechanism of the oxidation of Y2O3 coated and uncoated specimen is further discussed in this paper.
机译:本文研究了氧化钇(Y2O3)涂层对低合金9 Cr-1Mo钢的高温氧化行为的影响。制备的表面涂层是Y2O3,用于实验研究。在空气氧化环境中,在973 K下进行了8 h的未涂层和涂层样品的等温腐蚀研究。研究了腐蚀速率和反应动力学,并在SEM,EDS和XRD中表征了腐蚀后的水垢。结果清楚地表明,Y2O3涂层的样品比未涂层的样品具有更高的耐高温氧化性。在存在Y 2 O 3涂层的情况下,抗氧化性的改善可以归因于水垢生长机理的改变,从外阳离子迁移到内阴离子迁移,以及水垢与基材的粘附性增强。此外,在Y 2 O 3涂层的情况下,与基板的水垢附着力的增强还提高了抗氧化性。本文进一步讨论了Y2O3涂层和未涂层​​样品氧化的详细机理。

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