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Adsorption and inhibition effect of novel cationic surfactant for pipelines carbon steel in acidic solution

机译:新型阳离子表面活性剂在酸性溶液中对管道碳钢的吸附和缓蚀作用

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摘要

A new cationic surfactant was prepared and examined as an inhibitor for the corrosion of carbon steel in 1.0 M HCl solution using weight loss measurements, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization measurements. The chemical structure of the prepared cationic surfactants has been proven by FTIR spectra. The inhibiting effect of the cationic surfactant as a result of the formation of the protective layer adsorbed on the carbon steel surface The adsorption of the inhibitor was discussed accordingly to the Langmuir isotherm. Polarization data indicated that the cationic surfactant is a mixed-type inhibitor.. The effect of temperature on the corrosion rate of carbon steel in1. 0 M HCl solution devoid of and containing the novel cationic surfactant was examined and thermodynamic parameters were computed. Some surface parameters were calculated and explained.
机译:制备了一种新的阳离子表面活性剂,并通过重量损失测量,电化学阻抗谱(EIS)和电势极化测量,考察了其作为1.0 M HCl溶液中碳钢腐蚀的抑制剂。 FTIR光谱证明了所制备阳离子表面活性剂的化学结构。由于吸附在碳钢表面上的保护层的形成,对阳离子表面活性剂的抑制作用。相应于Langmuir等温线讨论了抑制剂的吸附。极化数据表明,阳离子表面活性剂是一种混合型缓蚀剂。温度对碳钢腐蚀速率的影响1。检查了不含和包含新型阳离子表面活性剂的0 M HCl溶液,并计算了热力学参数。计算并解释了一些表面参数。

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