Combustion Characteristics of Ammonium Nitrate and Carbon Mixtures Based on a Thermal Decomposition Mechanism

摘要

In order to obtain a better understanding of the combustion characteristics of ammonium nitrate (AN) and carbon (C) mixtures (AN/C), burning tests and differential scanning calorimetry (DSC) were performed. AN mixed with carbon that is oxidized by nitric acid (HNO3), such as activated carbon (AC), burned at 1 MPa. However, AN mixed with carbon that is not oxidized by HNO3, such as graphite, did not burn under 7 MPa. Compositions with more than stoichiometric amounts of activated carbon had higher burning rates. Heat characteristic examinations found a similar trend. The burning rate of AN/AC mixed with CuO as a combustion catalyst deteriorated faster than an additive-free one. From the DSC result, AN/AC/CuO had a higher onset temperature and a lower heat of reaction than AN/ AC. These results suggested that, in the combustion wave of AN/C, a thermal decomposition zone is formed on the burning surface, and combustion performance was affected by the thermal decomposition of AN/C.