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Kinetic rate equations in integrated form for single-step reactions involving different types of reactant

机译:涉及不同类型反应物的单步反应的整体形式动力学速率方程

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摘要

A method has been developed to obtain kinetic rate equations in integrated form for reactions involving two or three different types of reactant with different stoichiometries. The integrated rate equation of a reaction of desired order has been shown to be generated in a stepwise manner with the help of the integrated rate law(s) of lower order(s) by this procedure. The beauty of this procedure is that it is devoid of complicated integrations. This method has a particular mathematical importance, in that it can be used to solve first-order differential equations that involve different terms, each of which is associated with some arbitrary power.
机译:已经开发出一种方法来以积分形式获得涉及两种或三种不同化学计量比的反应物的反应动力学速率方程。已经证明,借助于该程序,借助于较低阶的积分速率定律,可以逐步生成期望阶次反应的积分速率方程。此过程的优点在于它没有复杂的集成。该方法具有特殊的数学重要性,因为它可用于求解涉及不同项的一阶微分方程,每个项都与某个任意幂相关联。

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