Synthesis, characterization and corrosion protection properties of poly(N-vinyl carbazole-co-glycidyl methacrylate) coatings on low nickel stainless steel

摘要

Methacrylate based copolymers are considered as one of the best organic coating materials for anticorrosive application. Poly(N-vinyl carbazole-co-glycidyl methacrylate) have been synthesized by free radical solution polymerization technique from different mole ratios of N-vinyl carbazole (N-Vc) and glycidyl methacrylate (GMA) and characterized using Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (~1H NMR and ~(13)C NMR). Thermal analyses of the poly(N-Vc-co-GMA) were performed by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The number average molecular weight (M_n) of different compositions of the same was determined by gel permeation chromatography (GPC). The corrosion performances of low nickel stainless steel specimens coated with different composition of copolymers were investigated in 1 M H_2SO_4 using potentiodynamic polarization, electrochemical impedance spectroscopic (EIS) method, scanning electron microscopic (SEM) and energy dispersive X-ray analysis (EDAX). Poly(N-Vc-co-GMA) have been provided in order to achieve adherent, low permeability to aggressive ions as well as environmentally favored good anticorrosive coating. Electrochemical corrosion test and surface analysis results clearly showed that poly(N-Vc-co-GMA) coatings served as a stable host matrix on low nickel stainless steel against corrosion. It was also observed that the coatings of poly(N-Vc-co-GMA) with equal mole ratio of N-Vc and GMA exhibited the best corrosion resistance among all combinations.