Anticorrosive properties of the epoxy-cardanol resin based paints

摘要

An epoxy-cardanol resin was developed using epichlorohydrin, bisphenol-A and cardanol. On evaluation it was found that epoxy-cardanol resin exhibits better properties as compared to epoxy resin in terms of increase in tensile strength, elongation, bond with steel and lowering of water vapour transmission of the film. The improvement in these properties indicated that the paints based on modified resin would be more durable than the epoxy based paints. Accordingly, paints were formulated using the developed resin and their performance were compared with their counterparts made with unmodified epoxy resin. Zinc powder, zinc phosphate, micaceous iron oxide and synthetic iron oxide were used as pigments along with fillers, additives and an aromatic polyamine adduct hardener. For both types of paints similar doses of pigments and additives were used. Physico-mechanical properties, chemical resistance and corrosion protection efficiency of the formulated paints were determined. It was found that the anticorrosive properties of epoxy-cardanol resin based paints are superior to that of the paints formulated with the unmodified epoxy resin. Micaceous iron oxide based paints in epoxy-cardanol resin showed the best performance followed by zinc phosphate based paints. It is concluded that the developed resin is a better binder media for the formulation of paints. (c) 2007 Elsevier B.V. All rights reserved.