An approach to synthesis of molecular reinforced polymeric materials: graft copolymerization of vinyl monomers from chloromethylated polyethersulfone via ATRP

摘要

Several approaches to make graft polymers involve in the preparation of suitable macroinitiators with functional groups capable of initiating ATRP. Frechet and coworkers developed a sequential two-step free radical approach, in which an initial nitroxide-mediated "living" free radical polymerization was followed by "living" ATRP. The graft copolymerization from chlorosulfonated polyethylene has also been reported.