In Situ Polymerization of Polyamide 66 Nanocomposites Utilizing Interfacial Polycondensation. II. Sodium Montmorillonite Nanocomposites

摘要

Interfacial polycondensation (IPC) is used to generate polyamide 66 (PA66) nanocomposite using sodium montmorillonite (NaMMT), which offers better thermal stability than organically modified montmorillonite. Several approaches are used to obtain different levels of dispersion for studying the factors affecting dispersion of NaMMT layered-silicates. These approaches include dispersing NaMMT in either aqueous media or in a compatible nonaqueous medium. Moreover, clay slurry was added to the reaction media separately or in combination with the aqueous hexamethylenediamine solution, which includes either excess amine or sodium carbonate as the by-product scavenger, in order to study the effect of sequencing on the dispersion of NaMMT. Several characterization techniques including dynamic mechanical analysis, wide angle X-ray diffraction, and transmission electron microscopy are used to examine the structure and relate it to the mechanical properties of the nanocomposites. Results show that in situ polymerization techniques predominantly give rise to hybrid exfoliated-intercalated NaMMT structure.