EFFICIENT CONVERSION OF THIOLS TO DISULFIDES BY 2,3-TETRAPYRIDINOPORPHYARZINOCOBALT(II)CATALYZED AEROBIC OXIDATION

Phillip Voegel; Jacob Shaffer

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EFFICIENT CONVERSION OF THIOLS TO DISULFIDES BY 2,3-TETRAPYRIDINOPORPHYARZINOCOBALT(II)CATALYZED AEROBIC OXIDATION

机译：2,3-四吡啶并卟啉锌钴（II）催化的好氧氧化有效地将硫醇转化为二硫

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The removal of thiols from petroleum products by sweetening involves catalytic oxidation of these compounds to disulfides in petroleum mixed with highly alkaline aqueous solutions in the presence of oxygen according to reaction one.Catalysis of this reaction by metal phthalocyanines (figure 1)has been the subject of extensive research.

机译：通过甜味脱除石油产品中的硫醇涉及在氧的存在下根据反应一将这些化合物催化氧化成石油与高碱性水溶液混合的二硫化物。金属酞菁对该反应的催化作用（图1）已成为主题广泛的研究。

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《Preprints》 |2006年第2期|共4页
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Phillip Voegel; Jacob Shaffer;
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正文语种 eng
中图分类石油、天然气加工工业;
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1. EFFICIENT CONVERSION OF THIOLS TO DISULFIDES BY 2,3-TETRAPYRIDINOPORPHYARZINOCOBALT(II)CATALYZED AEROBIC OXIDATION [J] . Phillip Voegel, Jacob Shaffer Preprints . 2006,第2期

机译：2,3-四吡啶并卟啉锌钴（II）催化的好氧氧化有效地将硫醇转化为二硫
2. Aerobic oxidation of thiols to disulfides catalyzed by a manganese(III) Schiff-base complex [J] . Hamid Golchoubian, Farideh Hosseinpoor Catalysis Communications . 2007,第4期

机译：锰（III）席夫碱配合物催化硫醇的好氧氧化为二硫化物
3. Efficient and practical synthesis of unsymmetrical disulfides via base-catalyzed aerobic oxidative dehydrogenative coupling of thiols [J] . Qiu Xu, Yang Xiaoxue, Zhang Yiqun, Organic Chemistry Frontiers . 2019,第13期

机译：通过碱催化的硫醇碱催化的有氧氧化脱氢偶联的不对称二硫化的高效和实际合成
4. Development of Highly Efficient Aerobic Oxidation of Alcohols Catalyzed by Guanidine-Pd Complex [C] . Masatoshi Kawahata, Hiroshi Danjo, Kentaro Yamaguchi Symposium on Organometallic Chemistry . 2007

机译：胍基Pd络合物催化高效好氧氧化的发展
5. Mechanistic studies of palladium-catalyzed 'Wacker type' intramolecular aerobic oxidative amination of alkenes and Development of safe and scalable continuous-flow methods for palladium-catalyzed aerobic oxidation [D] . Ye, Xuan 2010

机译：钯催化烯烃的“ Wacker型”分子内需氧氧化胺化的机理研究和开发安全，可扩展的连续流法进行钯催化的需氧氧化
6. Glutaredoxins employ parallel monothiol–dithiol mechanisms to catalyze thiol–disulfide exchanges with protein disulfides [O] . Ashwinie A. Ukuwela, Ashley I. Bush, Anthony G. Wedd, 2018

机译：戊二酸毒素利用平行的单硫醇-二硫醇机制催化二硫键与蛋白质二硫键的交换
7. Poly(N,N'-Dichloro-N-ethyl-benzene-1,3-disulfonamide) and N,N,N',N'-Tetrachlorobenzene-1,3-disulfonamide as Efficient Reagents to Direct Oxidative Conversion of Thiols and Disulfide to Sulfonyl Chlorides [O] . Hojat Veisi, Ramin Ghorbani-Vaghei, Jafar Mahmoodi 2011

机译：聚（N，N'-二氯-N-乙基 - 苯-1,3-二硫磺酰胺）和N，N，N'，N'-四氯苯-1,3-二磺酰胺，以直接氧化硫醇和二硫化物的氧化转化向磺酰氯
8. Reactive Oxygen Species Produced in Metal-Catalyzed Oxidation ofBis(Trifluoromethyl)Disulfide and Protection by ZE (Trademark) [R] . Arroyo, C. M., Kirby, S. D., Werrlein, R. J., 1994

机译：金属催化氧化双（三氟甲基）二硫化物产生的活性氧及ZE（商标）保护

EFFICIENT CONVERSION OF THIOLS TO DISULFIDES BY 2,3-TETRAPYRIDINOPORPHYARZINOCOBALT(II)CATALYZED AEROBIC OXIDATION

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