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EXPLORING FCC FLEXIBILITY TO PRODUCE MIDDISTILLATE AND PETROCHEMICALS

机译:探索FCC的灵活性以生产中等蒸馏和石化产品

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The FCC process was originally developed to convert vacuum gasoil (VGO)range hydrocarbons to high octane gasoline.Highly active acid catalysis provided by the conventional FCC Y zeolite catalyst is very successful in fulfilling this purpose.Large molecules boiling above 340oC are cracked to smaller molecules,initially forming olefins,which may continue to react and cyclize forming naphtenes,hydrogen transfer from naphtenic hydrocarbons,also promoted by the Y zeolite,produce aromatics halting further reactions [1].This reaction scheme is very convenient,as many of the C7 to C10 aromatics preferentially formed in the FCC are in the gasoline range and are also desirable for their high octane.
机译:FCC工艺最初是将真空瓦斯油(VGO)范围的烃转化为高辛烷值汽油而开发的,常规FCC Y沸石催化剂提供的高活性酸催化非常成功地实现了这一目标。沸点高于340oC的大分子被裂解为较小的分子,最初形成烯烃,可以继续反应并环化形成环烷烃,Y沸石也促进了环烷烃从氢的氢转移,产生了芳烃,阻止了进一步的反应[1]。这种反应方案非常方便,因为许多C7在FCC中优先形成的C10芳烃在汽油范围内,并且由于其高辛烷值也是理想的。

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