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Hydroprocessing Catalysis by New Reduced Ternary Molybdenum Sulfides

机译:新型还原三元硫化钼的加氢处理催化

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摘要

In our research, we have investigated a new series of hydroprocessing catalysts based on our discovery of the activity of the Chevrel phases (1). The family of Chevrel phase compounds has a characteristic structural unit based on the Mo_6S_8 cluster: the general composition is specified as M_xMo_6S_8, where M (the "ternary" metal cation) includes over 40 different metallic elements. Previous methods for preparing Chevrel phases usually have involved solid state syntheses at high temperatures (1000-1300 ℃). The resulting materials have low surface areas, typically around 1 m~2/g.
机译:在我们的研究中,我们基于对Chevrel相(1)活性的发现,研究了一系列新的加氢处理催化剂。 Chevrel相化合物家族具有基于Mo_6S_8簇的特征结构单元:一般成分指定为M_xMo_6S_8,其中M(“三元”金属阳离子)包含40多种不同的金属元素。先前制备Chevrel相的方法通常涉及高温(1000-1300℃)下的固态合成。所得材料具有低表面积,通常为约1m 2 / g。

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