Nonlinear Viscoelasticity of Fibre-filled Polypropylene Melts

摘要

Linears and non-linears viscoelastic properties play an important role in polymer processing. On addition of fillers (whether fibrous or particulate) the material's behaviour becomes very complicated. This paper presents the steady-state and dynamic viscoelastic properties of short carbon-fibre filled polypropylene (CF/PP) melts measured by a cone-plate type rheogoniometer. Storage and loss moduli were analyzed quantitatively by the Lissajous figures procedure (L method) as well as by Fourier series expansion (F method) to determine their respective higher order terms as the indicators of nonlinear viscoelasticity. The dependence of these components on fibre content and oscillatory angle, q was investigated. The results were compared with similar analytical data for CF filled liquid crystalline polymer (CF/LCP) melts. In the presently researched systems the CF content affects the viscosity, and at 15 and 20% an apparent yield stress appears. The complex viscosity is different for pure PP and its filled systems when measured as a function of theta. While for the unfilled polymer the viscoelasticity can be considered linear, for CF/PP some non-linearity must be taken into account, especially at higher value of theta. In general, the filled systems show complex viscoelastic behaviour with some irregularities, e.g. some of the higher order terms of the storage modules are negative, which was not seen in the previous study of fibre filled LCP systems.