Rheological signatures of ethylene methyl acrylate-multiwalled carbon nanotube nanocomposites

摘要

The rheological behavior of nanocomposites based on multiwalled carbon nanotube (MWNT) with three commercial grades of ethylene methyl acrylate (EMA) copolymers containing 9, 24, and 30 wt% methyl acrylate (MA) was investigated under dynamic and steady shear flow (in a capillary) conditions. Storage modulus (in dynamic shear) value increases especially at higher frequency levels due to increased polymer-filler interactions. Both the unfilled and filled composites exhibit rheological behavior of non-Newtonian fluids. In both steady shear and capillary flow, the nanocomposites register a slightly higher viscosity than neat EMAs, with dependence on the MWNTs content. All systems with various loading of MWNTs represent an increase in elastic response with increasing frequency. The die swell decreases with the MWNTs loading. Dynamic and steady shear rheological properties register a good correlation in regard to the viscous versus elastic response of such systems inline with the Cox-Merz concept. Increased MA content leads to inferior dispersion of MWNTs in EMA matrix. Morphological studies exhibit that MWNTs become more aligned along longitudinal direction after extrusion leading to improved dispersion.