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Preparation and Properties of Chloroprene Rubber (CR)/CIay Nanocomposites

机译:氯丁橡胶(CR)/ CIay纳米复合材料的制备与性能

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摘要

Chloroprene rubber (CR)/organic modifier/sodium montmorillonite (NA-MMT) nanocomposites were prepared by melt intercalation. The morphology of the nanocomposites was studied using X-ray diffraction (XRD) and transmission electron microscopy (TEM). TEM results showed that the silicate layers of the clay were dispersed in the CR matrix on the nano-scale by adding the organic modifier. X-ray diffraction also indicated that the silicate layers of clay were exfoliated. The mechanical and thermal properties of the nanocomposites could be therefore improved by adding clay and organic modifier, as the silicate layer of the clay was uniformly dispersed. Dynamic mechanical analysis was further performed to investigate the tbermomechanical properties of CR-clay nanocomposites containing various amounts of clay. The glass-transition temperature of CR- clay nanocomposites increased with increasing amount of clay and organic modifier.
机译:通过熔融插层法制备了氯丁橡胶(CR)/有机改性剂/蒙脱土钠(NA-MMT)纳米复合材料。使用X射线衍射(XRD)和透射电子显微镜(TEM)研究了纳米复合材料的形态。 TEM结果表明,通过加入有机改性剂,粘土的硅酸盐层以纳米级分散在CR基体中。 X射线衍射也表明粘土的硅酸盐层被剥落。因此,可以通过添加粘土和有机改性剂来改善纳米复合材料的机械性能和热性能,因为粘土的硅酸盐层被均匀分散。进一步进行动态力学分析以研究含有各种粘土的CR-粘土纳米复合材料的力学性能。 CR-粘土纳米复合材料的玻璃化转变温度随粘土和有机改性剂含量的增加而增加。

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