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Polymer Functionalisation Methods

机译:聚合物功能化方法

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摘要

Poly(D,L-lactic acid)-co-poly(ethylene glycol) copolymer was synthesised by melt polycondensation and irradiated with low energy electron beam in the presence of triallyl cyanurate and tetraallyl pentaerythritol as crosslinking agents. The highest tensile strength has been obtained at an energy of 80 and respectively 60kGy and decreased with further increase of the dose. The elongation at break decreased with the increase in dose as well. An increase of T_g is revealed as a result of the formation of a molecular network. Also a decrease in degradation of the polymer has been reported. It is suggested that the physical properties of the polymer network may be controlled by the radiation dose variation.
机译:在三烯丙基氰尿酸酯和四烯丙基季戊四醇作为交联剂的情况下,通过熔融缩聚反应并用低能电子束辐照合成聚(D,L-乳酸)-共聚(乙二醇)共聚物。在80kGy和60kGy的能量下获得了最高的抗拉强度,并且随着剂量的进一步增加而降低。断裂伸长率也随着剂量的增加而降低。由于分子网络的形成,揭示了T_g的增加。还已经报道了聚合物降解的降低。建议通过辐射剂量的变化来控制聚合物网络的物理性质。

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