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Rheological Investigations on the Flow Behavior of Polymer-Microsized Iron Powder Composites

机译:聚合物微粉铁粉复合材料流动行为的流变学研究

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With respect to the fabrication of metal parts carrying surface relief microstructures using composite reaction molding as a rapid prototyping variant of micrometal injection molding, the influence of microsized iron powder on the viscosity of different unsaturated polyester resins applied as polymer binder has been investigated systematically. The initial binder viscosity determines the viscosity of the composite and hence the accessible critical filler load. A further dilution of the unsaturated polyester resin with styrene allows a significant increase of the filler load at constant shear rate and temperature from 36 up to 57 vol% iron content. A successful estimation of the critical filler load using different established empirical models initially developed for ceramic-filled solutions or dispersions is possible. A pronounced flow activation energy increase at high iron loads was also observed.
机译:关于使用复合反应成型作为微金属注射成型的快速原型变体来制造带有表面浮雕微结构的金属零件,已经系统地研究了微粉铁粉对用作聚合物粘合剂的不同不饱和聚酯树脂粘度的影响。初始粘合剂粘度决定了复合材料的粘度,从而决定了可达到的临界填料载荷。用苯乙烯进一步稀释不饱和聚酯树脂可以使在恒定剪切速率和温度下填料的负载量显着增加,铁含量从36%提高到57%(体积)。使用最初为陶瓷填充溶液或分散体开发的不同建立的经验模型,可以成功地估计临界填料载荷。在高铁负载下也观察到明显的流动活化能增加。

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