Synthesis, characterization and X-ray crystal structure of the trigonal-planar copper(I) complex [Cu(MIBI)(3)](+) (MIBI=2-methoxyisobutylisocyanide)

Pasquali M; Ferretti V; Duatti A

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Synthesis, characterization and X-ray crystal structure of the trigonal-planar copper(I) complex [Cu(MIBI)(3)](+) (MIBI=2-methoxyisobutylisocyanide)

机译：三角平面铜（I）配合物[Cu（MIBI）（3）]（+）（MIBI = 2-甲氧基异丁基异氰化物）的合成，表征和X射线晶体结构

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摘要

The synthesis, spectroscopic and chromatographic characterization, and X-ray crystal structure of the complex tris(2-methoxyisobutylisocyano) copper(I) tetrafluoroborate, [Cu(MIBI)(3)][BF4], is reported. The Cu atom lies on threefold axis and is bonded to three 2-methoxyisobutylisocyano ligands in a perfect trigonal-planar coordination. The calculated and experimental powder-diffraction spectra of this complex are also reported. (C) 2008 Elsevier Ltd. All rights reserved.

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2008年第12期|共5页
作者
Pasquali M; Ferretti V; Duatti A;
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正文语种 eng
中图分类化学;
关键词
trigonal-planar copper complexes; copper isocyanide complexes; Cu-MIBI; Tc-99m-MIBI;

机译：三角平面铜配合物;异氰酸铜配合物;Cu-MIBI;Tc-99m-MIBI;

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Synthesis, characterization and X-ray crystal structure of the trigonal-planar copper(I) complex [Cu(MIBI)(3)](+) (MIBI=2-methoxyisobutylisocyanide)

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