A Theoretical Study of Chiral Recognition in Bis[amino(phenyl)methanol]chromium(0)Complexes

摘要

A theoretical study of the complexes formed by the chiral alpha-amino-alpha-phenylmethanol in the presence and absence of a chromium(0)atom has been carried out.The results indicate that in the presence of chromium,the most stable complex corresponds to that where the two amino(phenyl)-methanol molecules have the same chirality while in the absence of the mentioned atom the preferred one is that with the two molecules with different chirality.