Synthesis,Spectral and Structural Characteristics of Novel Complex Compounds of Ru(III),Rh(III)and Pd(II)with Typical and Atypical Ways of Coordination of 2-(3-Pyridilmethyliminomethyl)phenol

摘要

Ru(III),Rh(III)and Pd(II)metal complex of a 2-(3-pyridilmethyliminornethyl)phenol with typical and atypicaTways of coordination have been synthesized and characterized by elemental analyses,electronic,IR,H and C NMR spectra,and also by X-ray structure determination for the compounds in crystal form.It has been found that the coordination manner in obtained complexes depend mostly on synthesis conditions.