Synthesis and Characterization of a New 4-Methoxysalicyliden-p-aminoacetophenoneoxime and Its Complexes with Co(II),Cu(II) and Zn(II)

摘要

The novel Schiff base ligand,4-methoxysalicyliden-p-aminoacetophenoneoxime (LH) was synthesized starting from p-aminoacetophenoneoxime and 4-methoxysalicylalde-hyde.Mononuclear cobalt(II),copper(II) and zinc(II) complexes of the ligand have been prepared by using Co(II),Cu(II) and Zn(II) salt with a metal to ligand ratio of 1:2.The structures of the ligand and its complexes were identified by using elemental analyses,IR,~1H-and C-NMR spectra,magnetic susceptibility measurements,UV spectra and thermogravimetric analyses (TGA).