Sr/Ca–sea surface temperature calibration in the coral Porites lutea from subtropical northern South China Sea

摘要

Strontiumto calcium(Sr/Ca) ratios in annual bands of Porites corals are commonly used as past sea surface temperature proxy in tropical oceans, whereas studies that refer to Sr/Ca–SST calibration in high-latitude corals are rather rare in general. Here we present a 50-year (1961–2010) near-fortnightly Sr/Ca record in two Porites lutea corals living near the northern limit of reef-building corals in the subtropical northern South China Sea, where winter temperatures are extreme for hermatypic corals. The Sr/Ca time series shows a clear annual cyclicity, with marked sharparrow winter peaks. Comparison with an instrumental SST record (since 1961) indicates that this Sr/Ca record is chiefly modulated by SST. Two different methods are discussed for calibrating Sr/Ca with SST. The correlation between interpolated Sr/Ca and SST is significant, but the coefficient is relatively low, mainly attributed to extreme cold winter SSTs (<~16 °C) which cause a significant decrease or even cessation of coral skeletal extension. Another modified method using only annual low Sr/Ca values which could clearly bematchedwith the same features in the instrumental SST record ismore reliable. Themodified regression equation does not encompass SSTs below24 °C. The fidelity of the coral-based Sr/Ca–SST calibrationwas assessed and the precision of themethod is estimated to be 0.31 ± 0.62 °C based on the calibration–verification exercise. The modified method is suggested in marginal coral areas with extreme intra-annual SST variation (e.g., from 13 to 30 °C).