Densities, speeds of sound and refractive indices for binary and ternary mixtures of {diethylcarbonate (1) + p-chloroacetophenone (2)+1-hexanol (3)} at 303.15 K for the liquid region and at ambient pressure

摘要

Densities (), speeds of sound (u) and refractive indices (nD), of the ternary mixture (diethylcarbonate + p-chloroacetophenone + 1-hexanol) and the involved binary mixtures (diethylcarbonate + p-chloroacetophenone, diethylcarbonate + 1-hexanol, and p-chloroacetophenone + 1-hexanol) have been measured over the whole composition range at 303.15 K for the liquid region and at ambient pressure. The data obtained are used to calculate isentropic compressibilities ks, isentropic compressibility deviations ks and refractive index deviations nD, of the binary and ternary mixtures. The data of isentropic compressibility deviations and refractive index deviations of the binary systems were fitted to the Redlich-Kister equation while the best correlation method for the ternary system was found using the Cibulka equation. The experimental data of the constitute binaries and ternaries are analysed to discuss the nature and strength of intermolecular interactions in these mixtures.