Dynamics of the phase behavior of a polymer blend under shear flow

摘要

We study the dynamics of the phase behavior of a polymer blend in the presence of shear flow. By adopting a two-fluid picture and using a generalization of the concept of material derivative, we construct kinetic equations that describe the phase behavior of polymer blends in the presence of external flow. A phenomenological form for the shear modulus for the blend is proposed. The study indicates that a nonlinear dependence of the shear modulus of the blend on the volume fraction of one of the species is crucial for a shift in the stability line to be induced by shear flow. [S1063-651X(99)12501-7]. [References: 26]