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Preparation of carbon nanomaterials using two-group arc discharge plasma

机译:两组电弧放电等离子体制备碳纳米材料

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Carbon nanomaterials were prepared using two-group arc discharge plasma method in this study. A combination of an alternating current (AC) arc discharge plasma and a direct current (DC) arc discharge plasma in a fluidized bed was used, in which propane was cracked into carbon blacks (CB) with controlled structure and hydrogen. The effects of parameters such as electrode type, frequency of AC arc discharge, current of DC arc discharge and gas flow ratio (propane/argon) on the synthesis and properties of CB were investigated. A systematic study of the size, morphology, microstructure and surface chemical composition of CB was conducted using various characterization techniques. By using this process, spherical and hydrophobic CB with a narrow size distribution, high degree of graphitization and large specific surface area were produced under optimal experimental conditions. Then, as-prepared CB were used to adsorb heavy-metal ions in water and to reinforce the engineering plastic. The results verified that the adsorption rate of the Cr (VI) ion was increased significantly and that the CB enhanced the electrical and mechanical properties of acrylonitrile-butadiene-styrene (ABS)atural rubber (NR) composites. (C) 2016 Elsevier B.V. All rights reserved.
机译:在本研究中,采用两组电弧放电等离子体方法制备了碳纳米材料。使用流化床中的交流(AC)电弧放电等离子体和直流(DC)电弧放电等离子体的组合,其中将丙烷裂解为结构受控的炭黑(CB)和氢。研究了电极类型,交流电弧放电频率,直流电弧放电电流和气体流量比(丙烷/氩气)等参数对CB的合成和性能的影响。使用各种表征技术对CB的大小,形态,微观结构和表面化学组成进行了系统研究。通过这种方法,在最佳实验条件下生产了具有窄尺寸分布,高石墨化度和大比表面积的球形和疏水性炭黑。然后,将制得的CB用于吸附水中的重金属离子并增强工程塑料。结果证明,Cr(VI)离子的吸附速率显着提高,并且CB增强了丙烯腈-丁二烯-苯乙烯(ABS)/天然橡胶(NR)复合材料的电气和机械性能。 (C)2016 Elsevier B.V.保留所有权利。

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