Effect of Drawdown on Ammonium and Iron Concentrations in a Coastal Mountain Reservoir

摘要

part way through a year-long water quality field survey, the Capilano Reservoir, located in the Greater Vancouver Water District, was drawn down to accommo- date earthquake reinforcement work on the Cleveland Dam. This paper reports observations of the effect of drawdown on water quality in the reservoir, in the context of the original study The drawdown exposed a large zone of deltaic material through which the Capilano River eroded a path up to 2.5 m deep. The deltaic material contained substantial amounts of nitrogen and iron (TKN, 4,470 mg· kg~(-1); total iron, 21.800 mg· kg~(-1)). During drawdown, turbidity in the reservoir increased up to 25 times as compared to prior conditions. Ammonium (NH_4~+ -N) and dissolved and particulate iron concentrations in the drawdown zone were up to two orders of magnitude higher than concentrations upstream. Both NH_4~+ -N and dissolved iron were observed to travel the length of the reser- voir. Persistence of NH_4`+ -N in the highly oxygenated conditions may be ex- plained by the presence of factors that inhibit nitrification. Persistence of NH_4~+ -N and particularly dissolved iron may be due to adsorption and com- plexation reactions. Seasonally high concentrations of iron and ammonium at the water intake corresponded to the timing of complaints of taste, odour, tur- bid water, and staining in the distribution system. Observations made during this extreme drawdown suggest that transport of N and Fe from exposed delta- ic sediments may play a role in the periodic increases in ammonium and iron observed in the Capilano Reservoir. Further understanding of the impacts asso- ciated with changing reservoir elevation should lead to the development of appropriate management strategies to maintain the high quality of GVWD water.