Optimization of plasma-enhanced chemical vapor deposition silicon oxynitride layers for integrated optics applications

摘要

Silicon oxynitride (SiO_xN_y:H) layers were grown from 2%SiH_4/N_2 and N_2O gas mixtures by plasma-enhanced chemical vapor deposition (PECVD). Layer properties such as refractive index, deposition rate, thickness non-uniformity and hydrogen bond content were correlated to the relevant deposition parameters including radio frequency power, chamber pressure, total gas flow, substrate temperature and N_2O/SiH_4 gas flow ratio. As a result, optimized SiO_xN_y:H layers could be produced over a wide index range (1.46-1.70) with good thickness uniformity and sufficiently high deposition rate. With a refraction index non-uniformity < 5 x 10~(-4) a thickness non-uniformity could be obtained below 1% over a 70 x 70 mm~2 area of a 100 mm wafer at a deposition rate > 50 nm/min. The material composition and the optical properties of the SiO_xN_y:H layers were characterized by spectroscopic ellipsometry, X-ray Photoelectron Spectroscopy, Fourier Transform Infrared spectroscopy and prism coupler techniques. A simple atomic valence model is found to describe the measured atomic concentrations for PECVD silicon oxynitride layers.