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Oxidation and hot corrosion behavior of sputtered nanocrystalline coating of superalloy K52

机译:溅射K52纳米晶涂层的氧化和热腐蚀行为。

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Nanocrystalline coating on the cast K52 alloy was prepared by magnetron sputtering from the target of the same alloy. The comparison of oxidation in air at 800-1000 ℃ and hot corrosion under molten Na_2SO_4+25 wt.% K_2SO_4 at 850 ℃ of the cast alloy and its nano-grained counterpart was investigated by means of TGA and XRD. The result showed that the nanocrystallization of the cast alloy led to a transformation of the alloy from a chromia former to an alumina former, and consequently a greatly reduced oxidation rate. Besides, the alumina scale formed on the nanocrystalline coating was much adherent compared to the chromia scale on the cast alloy. In contrast, the increase of the hot corrosion resistance was not significant for the nanocoating with regard to the cast alloy.
机译:通过磁控溅射从相同合金的靶材上制备了铸造K52合金上的纳米晶涂层。利用TGA和XRD研究了铸造合金及其纳米晶合金在800-1000℃的空气中的氧化和熔融Na_2SO_4 + 25 wt。%K_2SO_4在850℃下的热腐蚀的比较。结果表明,铸造合金的纳米晶化导致合金从氧化铬形成剂转变为氧化铝形成剂,因此大大降低了氧化速率。此外,与铸造合金上的氧化铬鳞片相比,在纳米晶体涂层上形成的氧化铝鳞片具有更大的粘附性。相反,对于纳米涂层,相对于铸造合金,耐热腐蚀性的增加并不显着。

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