Efficient fluorescent red, green, and blue organic light-emitting devices with a blue host of spirobifluorene derivative

摘要

Efficient fluorescent blue, green, and red (RGB) organic light-emitting devices (OLEDs) were fabricated using a blue host material of pyrimidine-containing spirobifluorene derivative 2,7-bis[2-(4-tert-butylphenyl)pyrimidine-5-yl]-9,9'-spirobifluorene (TBPSF) doped with blue dye perylene, green dye 10-(2-benzothiazolyl)-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-benzo[1] pyrano[6,7,8-ij] quinolizin-11-one (C545T), and red dye 4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB), respectively. The brightness and current efficiency of the perylene doped blue device reached 10117 cd/m~2 and 2.97 cd/A. Green emission of the C545T doped device reached 8500 cd/m~2 and 13.0 cd/A. Red emission of the DCJTB doped device can be as high as 9000 cd/m~2 and 2.0 cd/A, respectively. High color purity of the blue (Commission Internationale de L'Eclairage (CIE_(x,y)) coordinates (CIE, x=0.27,y=0.24)), green (CIE, x = 0.19, y=0.63) and red (CIE, x=0.62, y=0.37) emissions were achieved for RGB dyes doped TBPSF OLEDs. High brightness, large current efficiency, and good color purity of TBPSF-based RGB OLEDs were obtained by the configuration optimization device, such as inserting the hole and electron-injection materials, and suitable dopant content and light emitting layer thickness.