Luminescence mechanisms of organic/inorganic hybrid organic light-emitting devices fabricated utilizing a Zn_2SiO_4:Mn color-conversion layer

摘要

Zn_22SiO_44:Mn phosphor layers used in this study were synthesized by using the sol-gel method and printed on the glass substrates by using a vehicle solution and a heating process. Organic/inorganic hybrid organic light-emitting devices (OLEDs) utilizing a Zn_2SiO_4:Mn color-conversion layer were fabricated. X-ray diffraction data for the synthesized Zn_2SiO_4:Mn phosphor films showed that the Zn ions in the phosphor were substituted into Mn ions. The electroluminescence (EL) spectrum of the deep blue OLEDs showed that a dominant peak at 461 nm appeared. The photoluminescence spectrum for the Zn_2SiO_4:Mn phosphor layer by using a 470 nm excitation source showed that a dominant peak at 527 nm appeared, which originated from the ~4T_1-~6A_1 transitions of Mn ions. The appearance of the peak around 527 nm of the EL spectra for the OLEDs fabricated utilizing a Zn_2SiO_4:Mn phosphor layer demonstrated that the emitted blue color from the deep blue OLEDs was converted into a green color due to the existence of the color-conversion layer. The luminescence mechanisms of organic/inorganic hybrid OLEDs fabricated utilizing a Zn_2SiO_4:Mn color-conversion layer are described on the basis of the EL and PL spectra.